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We first generated initial guesses for all the transition state coordinates, informed by the distances of a model transition state [CH 3 S … HOOH] –

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While excess ROS can cause toxicity, macrophages and neutrophils contain an NADPH oxidase which produces ROS to destroy foreign organisms (24), and the enzyme myeloperoxidase catalyzes a reaction between H 2 O 2 and chloride to produce the powerful oxidant hypochlorite (bleach) to help destroy foreign invaders