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Identification of cytosolic leucyl aminopeptidase (EC 3.4.11.1) as the major cysteinylglycine hydrolysing activity in rat liver

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In the oxidative half of the mechanism, Cys63 nucleophilically attacks the nearest sulfide unit in the glutathione disulfide (GSSG) molecule, which creates a mixed disulfide bond (GS-Cys58) and a GS- anion

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